Secret agent (like James Bond) - why not? He's got it all: guns, gadgets, and girls.
Official Taster at a German brewery - to get the best stuff.
Hit man for the Chicago mob - they've always set the standard.
Airline pilot - love their paychecks and hours worked per month ratio.
Oh - you meant ones we actually had a shot at achieving? Then I'll go for Database Administrator, since I've bought a test prep book to start on my MCDBA.