Eruptive and diffuse emissions of CO2 from Mount Etna - P. Allard, et al., Nature 351 30 May 1991, p.387
[...]
According to these results, Etna is an important emitter of volcanic carbon dioxide. Although it makes up only 0.07% of the annual anthropogenic CO2 loading (2 x 10^4 Tg; ref 34), its CO2 discharge by sustained crater degassing (13 +/- 3 Tg/yr) is one order of magniture higher than the annual CO2 output from Kilauea 7,8 and actively degassing arc volcanoes 9,10 (Table 2). [...]
Yes, that's just one volcano, but Etna is a big contributor and it pales in contrast with the anthropogenic (man-made) CO2 contributions.
The HTML for the 150x link was busted. Here is the [link|http://volcano.und.nodak.edu/vwdocs/Gases/man.html|correct link]. The original paper (by Gerlach, also a paper on Etna in Nature) is [link|http://www.nature.com/nature/journal/v351/n6325/pdf/351352a0.pdf|here]:
Mount Etna emits CO2 gas at an astonishing rate - 25 million tons a year is the conservative estimate of Allard et al. on page 387 of this issues 1. This equals the output of four 1,000 MW coal-fired power stations. Active volcanoes on land typically pump out CO2 at rates more like 0.1 - 2 million tons a year [...]
HTH.
Cheers,
Scott.