
Let's see... 45 kB images.
[link|http://volcanoes.usgs.gov/Hazards/What/VolGas/volgas.html|USGS]:
Volcanoes release more than 130 million tonnes of CO2 into the atmosphere every year.
[link|http://www.eia.doe.gov/oiaf/1605/ggccebro/chapter1.html|EIA]:
[image|http://www.eia.doe.gov/oiaf/1605/ggccebro/images/New%20Fig%201.gif|0|Graph of Man-made CO2 emissions and atmospheric concentration|262|411]
It looks like your numbers are off a little bit. It looks to me like we've been putting more than 130 million tonnes a year of CO2 into the atmosphere since about 1860. It's presently about 6.1 B tonnes per year (or volcanoes are about 2.1% of the anthropogenic CO2).
The next figure shows the circulation of carbon in the atmosphere, in B tonnes per year:
[image|http://www.eia.doe.gov/oiaf/1605/ggccebro/images/NewFlowFig2.gif|0|Carbon cycle in B tonnes/year|351|603]
The 6.1 B tonnes we add every year is a small percentage of the total available carbon. But note that the blue arrows are nearly in balance while the red (human activity) arrows are forcing things in a particular direction. Termites can knock over a redwood if they're persistent enough...
[edit:] A more detailed graph of the carbon cycle is [link|http://www.vitalgraphics.net/graphic.cfm?filename=climate2/large/11.jpg|here] (135 kB image). It doesn't include volcanoes (if they're really 130 MT/yr, they are too small a contribution to show up).
Cheers,
Scott.