When the pavement gets warm enough, it has a tendency to heat up your tires. Which heats up the air in your tubes. Which causes the pressure in the tubes to rise. Which could cause a blow-out.
Happened to more than a few people on last year's AIDSRide, and the temp was only 75-85.
I just completed the Chicago-based MS 150 ride (Chicago to Kankakee to Chicago) this weekend. 162 miles. 100 degrees on Saturday, 103 on Sunday. I lost 7 pounds. Oh, and there were a few over-pressurization tire pops.