Provisos/comments:
Opera's shite.
Kopete is great for regular IM work, but hopeless for IRC. Yes, X-Chat will be required.
The install is truly fabulous.
It couldn't find a working Audigy2 driver, though; the emu10k1 driver it installed produced no noise.
I like the way it gives you two desktops by default *with different coloured backgrounds*. This is an excellent visual cue.
I couldn't play a DVD out of the box.
I concur with your overall assessment; it's very polished and there's been a lot of work done here.