It was theoretically possible to break them, but your average person couldn't do it on demand.
In fact there was a famous example of one lawyer who used to demonstrate this to clients. He would run full tilt into the window and it would hold. Unfortunately for him, he was in the habit of always using the same window for the demonstration, and eventually the repeated abuse caused it to give way.
However despite his eventual success, it wasn't something that you could just choose to do in an emergency. The windows that you saw broken were broken by the plane, not by the people who jumped out of them.
Cheers,
Ben